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Powder coating is by far the youngest of the surface finishing
techniques in common use today. It was first used in Australia about
1967. Powder coating is the technique of applying dry paint to a part.
The final cured coating is the same as a 2-pack wet paint. In normal wet
painting such as house paints, the solids are in suspension in a liquid
carrier, which must evaporate before the solid paint coating is
produced.
In powder coating, the powdered paint may be applied by either of two
techniques.
- The item is lowered into a fluidised bed of the powder, which may
or may not be electrostatically charged, or
- The powdered paint is electrostatically charged and sprayed onto
the part.
The part is then placed in an oven and the powder particles melt and
coalesce to form a continuous film.
There are two main types of powder available to the surface finisher:
- Thermoplastic powders that will remelt when heated, and
- Thermosetting powders that will not remelt upon reheating. During
the curing process (in the oven) a chemical cross-linking reaction is
triggered at the curing temperature and it is this chemical reaction
which gives the powder coating many of its desirable properties.
Preparation
The basis of any good coating is preparation. The vast majority of
powder coating failures can be traced to a lack of a suitable
preparation.
The preparation treatment is different for different materials.
In general, for all applications the preparation treatment for
aluminium is as follows:
| Clean |
Or
|
Clean |
| Rinse |
|
Rinse |
| Etch |
|
Etch |
| Rinse |
|
Rinse |
| Chromate |
|
Phosphate |
| Rinse |
|
Rinse |
| Demin Rinse |
|
Demin Rinse |
Oils and greases are removed in weak alkali or neutral detergent
solutions and the surface is etched to remove heavy oxides. After
rinsing, the aluminium is dipped into a chromate or phosphate solution
to form a conversion coating on the aluminium. This film is chemically
attached to the aluminium. After rinsing the aluminium is finally rinsed
in demineralised water. Some non-chrome, dried in place pretreatment is
beginning to come onto the market; currently, these are not recommended
for exterior applications.
The conversion coating has two functions:
- It presents a surface to the powder which favours adhesion more
than the oxides that form very readily on aluminium surfaces, and
- It reduces the incidence of under film corrosion, which may occur
at holidays in the coating.
The use of demineralised water reduces the presence of chemical salts
on the aluminium surface. These salts have been found to cause filiform
corrosion in humid conditions.
For steel the preparation for interior applications may be:
| Clean |
| Rinse |
| Derust |
| Rinse |
| Iron Phosphate |
| Rinse |
| Acidulated Rinse |
For exterior applications:
| Clean |
| Rinse |
| Etch |
| Rinse |
| Grain Refine |
| Zinc Phosphate |
| Rinse |
| Acidulated Rinse |
The grain refiner is used after acid cleaning of steel surfaces and
before zinc phosphating, otherwise the zinc phosphate coatings produced
will be very coarse with low adhesion. The powder coating applied to a
coarse phosphate will produce rough coatings (a little like "sandpaper")
and possess low adhesion.
For hot dipped galvanized coatings, which have been stored for more
than about 4 hours before powder coating, the following process is
necessary for exterior applications.
| Clean |
| Rinse |
| Etch |
| Rinse |
| Grain Refiner |
| Rinse |
| Zinc Phosphate |
| Acidulated Rinse |
The etch is required to remove the zinc corrosion products which
begin to form almost immediately the zinc is removed from the
galvanizing kettle. The grain refiner ensures a fine phosphate is
produced.
How is it done -- electrostatic spray?
The powder is applied with an electrostatic spray gun to a part that
is at earth (or ground) potential.
Before the powder is sent to the gun it is fluidised:
- to separate the individual grains of powder and so improve the
electrostatic charge that can be applied to the powder and
- so that the powder flows more easily to the gun.
Because the powder particles are electrostatically charged, the
powder wraps around to the back of the part as it passes by towards the
air offtake system. By collecting the powder, which passes by the job,
and filtering it, the efficiency of the process can be increased to 95%
material usage.
The powder will remain attached to the part as long as some of the
electrostatic charge remains on the powder. To obtain the final solid,
tough, abrasion resistant coating the powder coated items are placed in
an oven and heated to temperatures that range from 160 to 210 degrees C
(depending on the powder).
Under the influence of heat a thermosetting powder goes through 4
stages to full cure.
MELT, FLOW, GEL, CURE
The final coating is continuous and will vary from high gloss to flat
matt depending on the design of the powder by the supplier.
Powder coating guns
There are at east three types of electrostatic guns in use:
- Corona charging guns where electric power is used to generate the
electrostatic charge. Corona guns are either internal or external
charging.
- Tribo charging guns where the electrostatic charge is generated by
friction between the powder and the gun barrel.
- "Bell" charging guns where the powder is charged by being "flung"
from the perimeter of the "bell"
Not all powder is applied using guns. One system makes use of
electrostatic tunnels.
How is colour introduced?
Colour is added to powder coatings during the manufacturing process,
ie before the powder reaches the powder coater. There is little that can
be done to change the colour consistently, once the powder leaves the
manufacturing plant.
Why powder coat?
Powder coating produces a high specification coating which is
relatively hard, abrasion resistant (depending on the specification) and
tough. Thin powder coatings can be bent but this is not recommended for
exterior applications.
The choice of colours and finishes is almost limitless, if you have
the time and money to have the powder produced by the powder
manufacturer.
Powder coatings can be applied over a wide range of thickness. The
new Australian Standard, "AS/NZS 4506 - Thermoset powder coatings", will
recommend 25 micron minimum for mild interior applications and up to 60
micron minimum for exterior applications. Care must be exercised when
quoting minimum thickness because some powder will not give "coverage"
below 60 or even 80 micron. "Coverage" is the ability to cover the
colour of the metal with the powder. Some of the white colours require
about 75 micron to give full "coverage". One of the orange colours must
be applied at 80 micron.
Colour matching is quite acceptable batch to batch.
Installations and maintenance
During installations, the powder coating should be protected from
damage due to abrasion and materials of construction such as mortar and
brick cleaning chemicals.
Once installed, maintaining the initial appearance of a powder
coating is a simple matter. The soot and grime which builds up on
surfaces from time to time contains moisture and salts which will
adversely affect the powder coating and must be removed. Powder coatings
should be washed down regularly (at least once each 6 months in less
severe applications and more often in marine and industrial
environments). The coating should be washed down with soapy water -- use
a neutral detergent -- and rinsed off with clean water.
When powder coated items are installed without damage to the powder
coating and they are maintained regularly, they should be relatively
permanent. The correctly applied coating, although not metallurgically
bonded to the metal will not crack, chip or peel as with conventional
paint films. |