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The process of extruding two or more materials through a single die with
two or more orifices arranged so that the extrudates merge and weld
together into a laminar structure before chilling. Each material is fed
to the die from a separate extruder, but the orifices may be arranged so
that each extruder supplies two or more plies of the same material.
Coextrusion can be employed in film blowing, free film extrusion, and
extrusion coating processes. The advantage of coextrusion is that each
ply of the laminate imparts a desired characteristic property, such as
stiffness, heat-sealability, impermeability or resistance to some
environment, all of which properties would be impossible to attain with
any single material.
The facts about Co-extrusion
Advantages
“Coextrusion is another tool in the well-outfitted converter's tool
chest,” according to Bruce Foster, technical sales manager of Mica Corp.
“It provides better quality monolayer extrusion coatings over a wider
variety of widths and line speeds; the potential to save on the amount
of premium resins by filling with lower cost materials; and the
possibility to make multi-layer, multi-functional structures in a single
pass.”
A group at Battenfeld Gloucester Engineering Co. feel that
coextrusion offers targeted performance using specific polymers in
specific layers, a reduction in the number of process steps, and lower
cost, says spokesperson Bill Hellmuth, senior product manager — blown
film systems.
Hellmuth states lower cost is possible because of the reduced amount
of expensive polymer for equal performance, the use of inexpensive
polymers without sacrificing performance, a reduction in setup and trim
scrap, and the potential for use of a recycle layer.
Scott B. Marks, senior technical specialist at E.I. duPont de Nemours
& Co., Packaging & Industrial Polymers, divides the coextrusion process
into two main uses — non-barrier and barrier applications. “In the
non-barrier applications, coextrusion allows a converter to maximize the
properties he needs in a given structure such as sealing
characteristics, coloration, opacity, and physical properties. For
barrier application, coextrusion allows incorporation of a barrier layer
to control transmission of oxygen, carbon dioxide, water vapor, etc.”
“Handling resins that could not run on their own” is a characteristic
of coextrusion that David Timm, VP of Charter Films, considers an
advantage.
Disadvantages
“The disadvantage of coextrusion is that some differences in physical
properties that make a combination desirable also make the combination
incompatible,” says Gary D. Oliver, senior corporate scientist at
Cloeren Inc. “Polymers for coextrusion should have similar melt
viscosities to maintain laminar flow. Viscosity differences can be more
or less tolerable depending on the location of the material in the
composite structure and the thinness of the layer.”
Andy Christie, principal consultant of Optex Process Solutions, notes
coextrusion has three disadvantages: It requires a more sophisticated
extruder operator; it necessitates significant planning and forethought
in system design; and it provides the potential to create expensive
scrap quickly.
Richard W. Halle, senior staff engineer at ExxonMobil Chemical Co.,
observes the biggest disadvantage of coextrusion is “probably that the
added complexity of the equipment means added maintenance cost.”
In an interesting comment regarding cost, Timm says, “Many people
might consider the first disadvantage of coextrusion to be cost. I do
not. Depending on the intricacies of die design, coextrusion dies can be
difficult to purge and can be prone to buildup especially with barrier
materials. Improvements in materials and die design can minimize such
degradation problems.”
Application Advances
Expanded markets and uses are other focal points for capitalizing on the
advantages of coextrusion and trying to reduce the influence of its
disadvantages. Foster's thinking in this area is simple: “Anywhere you
see a rigid package today, you may see a flexible package next year.”
Perdikoulis offers a very futuristic remark: “Advanced control
systems ultimately will have some simulation capability or
‘intelligence’ that will allow users to select the properties they want
in a product, and the control system will specify the structure. Imagine
selecting the shelf life requirements, strength, and heat seal
characteristics and having the control system select the materials and
adjust the layer ratios accordingly.”
“Applications and markets will continue to diversify into what we now
call the ‘industrial segments,’” according to Marks. “The need for
property enhancement and economics drove coextrusion into the packaging
film industry. In the market for ‘industrial films and laminations,’
this need for coextrusion is now accelerating. Functionality needs vs.
direct economic needs of an extrusion drive this today. Economic needs
relate more to altering the assembly process, simplifying the assembly
process, or both. Combining the technical advantages with product
assembly changes may reduce total costs. In cases where it does not, the
technical advantages are sufficient to propel coextrusion growth.”
Oliver notes the recent appearance of a hybrid container that is a
multilayer coated paperboard. “We are seeing this round container show
up more frequently in the United States and in more large-size liquid
container boxes that have been prevalent in Europe for some time. I
think another application that will continue to grow is the stand-up
pouch.”
Looking at coextrusion growth globally, Christie notes, “Second and
Third World markets will bypass many recent technologies and jump to
leading-edge technology as they invest in new equipment and develop
products for internal consumption and export.”
Hellmuth's group reports “food and water packaging will top the list
of products as the world strives to feed itself. Housing market pressure
will push plastics to the forefront in an effort to conserve natural
resources and provide an outlet for plastic package recycling. The group
at Equistar Chemical thinks converters will find creative ways to use
coextrusion to replace many laminated structures because of cost
pressures and intensified competition: “This will involve a combination
of resin engineering, equipment engineering, and innovation. The market
also will see a significant jump in down gauging for certain
applications that already seem over-engineered in total gauge. The
‘supply chain’ will drive creativity by accessing vantage points and
knowledge bases that were previously not on the table for discussion.
This will lead to new models for doing business and developing new
products.” |